Modeling pore size distribution in cellulose rolled stationary phases.

Rolled stationary phases are fabrics (i.e., nonparticulate phases) that rapidly separate proteins from salts on the basis of size exclusion. Pore size and pore size distributions in the stationary phase determine how different size molecules distribute between the stationary and mobile phases in liquid chromatography columns. The potential for size exclusion chromatography by fabrics is not initially obvious because their interlaced structures are atypical for size exclusion supports. A simple logistic model fits the pore size distribution of a rolled stationary phase when pore sizes were measured using PEG, Dextran, D2O, glucose, and NaCl probes. When the fabric is treated with cellulase enzymes, the water-accessible pores uniformly decrease and peak retention is lower. The logistic function model captures this result and enables comparison of pore size distribution curves between enzyme-treated and untreated fabrics in rolled stationary phase columns.

[Recovery and use of deuterium-free water in extended space expeditions]. / Poluchenie i ispol'zovanie bezdeiterievoi vody v usloviiakh dlitel'nykh kosmicheskikh ékspeditsii.

The methods of deuterium-free water, as applied to the conditions of long-term space expeditions have been discussed. It is shown that with the use of the method of electrolysis of distilled water or urine condensate followed by the catalytic or high-temperature synthesis one can obtained water with four-fold decrease in deuterium concentration. In order to reduce the energy expenditure it is necessary to use the existing routine technologies of water and oxygen regeneration or the versions with applying the fuel cells in which hydrogen and oxygen resulting from electrolysis would generate the electrical power with simultaneous isolation of deuterium-free water.