RESUMO
This review focuses on the trends in contrast media (CM) research published in Acta Radiologica during the last 100 years, since the first edition in 1921. The main topics covered are the developments of iodine- and gadolinium-based CM. Other topics include manganese-based CM for magnetic resonance imaging (MRI) and barium for the investigation of the alimentary tract. From a historic point of view, special CM for use in cholegraphy and myelography are addressed in the review. Today, these imaging procedures are obsolete due to the development of computed tomography, MRI, and ultrasound. The historical use of radioactive thorium-based CM for angiography is also addressed. Furthermore, publications on adverse reactions to CM are reviewed.
Assuntos
Meios de Contraste/história , Publicações Periódicas como Assunto/história , Pesquisa/história , Bário/história , Bibliometria , Ductos Biliares/diagnóstico por imagem , Meios de Contraste/efeitos adversos , Meios de Contraste/farmacologia , Gadolínio/história , História do Século XX , História do Século XXI , Humanos , Iodo/história , Imageamento por Ressonância Magnética , Manganês/história , Mielografia/históriaRESUMO
This article describes the complementary application of non-invasive micro-Raman spectroscopy and energy dispersive X-ray fluorescence spectrometry to the characterization of some ancient Chinese silicate artifacts. A total of 28 samples dated from fourth century BC to third century AD were analyzed. The results of chemical analysis showed that the vitreous PbO-BaO-SiO2 material was used to sinter these silicate artifacts. The barium copper silicate pigments including BaCuSi4O10, BaCuSi2O6 and BaCu2Si2O7 were widely identified from colorful areas of the samples by Raman spectroscopy. In addition, other crystalline phases such as Fe2O3, BaSi2O5, BaSO4, PbCO3 and quartz were also identified. The present study provides very valuable information to trace the technical evolution of man-made barium copper silicate pigments and their close relationship with the making of ancient PbO-BaO-SiO2 glaze and glass.
Assuntos
Bário/história , Cobre/história , Silicatos/história , Espectrometria por Raios X , Análise Espectral Raman , China , Cristalização , Vidro , História AntigaRESUMO
On the basis of the reconstruction of general nutritional patterns by trace element data on historic populations, an examination on occupational Ba intakes in the skeleton was carried out for a historical metallurgy population. The concentrations of the trace elements Ba, Sr, and Pb as well as the matrix element Ca were determined by AAS analysis. Their correlations within the population were analysed statistically. Evidence of a correlation between Ba and Sr concentrations and the lack of a correlation between Ba and Pb concentrations is interpreted as evidence for a probably solely dietary-related Ba intake in the skeleton. Ba intake from working in ore smelting plants is therefore unlikely or at least insignificant. These conclusions are supported by analysis results of modern food items from the catchment area of the historical population. A sufficient Ba supply through rye was determined, thereby explaining the concentration of Ba in the bone material of the historic population.
