Estudio in vitro del ajuste de supraestructuras pasivadas sobre implantes múltiples / In vitro study of the adjustment of passivated suprastructures on multiple implants

Objetivo: Comparar dos procedimientos de soldadura convencionales empleando una aleación de Cr-Co, para co- nectar barras coladas seccionadas a ser fijadas sobre implantes. Materiales y métodos: A partir de un modelo maes- tro que representa un maxilar desdentado con cuatro implan- tes, se confeccionaron veinte (n=20) probetas seccionadas en tres partes. Se conformaron dos grupos, cada uno con diez (n=10) ejemplares. Una vez acondicionadas, fueron atornilla- das al modelo maestro. Su desajuste inicial se analizó utili- zando una lupa estereoscópica, con una cámara incorporada y un software. Las partes fueron soldadas empleando un pro- cedimiento diferente para cada grupo. Las correspondientes al Grupo I se invistieron en un block refractario a base de sílico-fosfato. Las del Grupo II se montaron en una estructu- ra metálica Clever Spider. El desajuste fue mensurado y los resultados procesados estadísticamente. El nivel de significa- ción fue establecido en p<0,05. Resultados: El Grupo I tuvo un desajuste inicial de 97,30±13,81µm y el Grupo II de 98,53±11,24µm. Luego de la soldadura, el Grupo I registró 98,53±17,17µm, 1,23µm mayor respecto al inicial. En el Grupo II se observó 103,13±17,61µm, 4,60µm por encima del original. Se analizaron mediante prue- ba t de Student; en ambos casos el resultado fue de p>0,05. Al comparar entre sí los grupos I y II, por medio de la prueba t y de comprobación no paramétrica de Mann-Whitney, se ob- servaron diferencias no significativas, p=0,41 y p=0,38 res- pectivamente (AU)

Aim: Compare two conventional welding procedures us- ing a Cr-Co alloy, to connect sectioned cast bars to be fixed on implants. Materials and methods: From a master model representing a toothless jaw with four implants, twenty (n=20) specimens sectioned into three parts were made. Two groups were formed, each with ten (n=10) specimens. Once conditioned, they were screwed to the master mod- el. Its initial mismatch was analyzed using a stereoscop- ic magnifier, with a built-in camera and a software. The parts were welded using a different procedure for each group. Those corresponding to Group I were invested in a refractory block based on silyl-phosphate. Those of Group II were mounted on a Clever Spider metal structure. The mismatch was measured, and the results processed statisti- cally. The level of significance was established at p<0.05. Results: Group I had an initial mismatch of 97.30 ±13.81µm, and Group II of 98.53±11.24µm. After welding, Group I registered 98.53±17.17µm, 1.23µm higher than the initial one. In Group II, 103.13±17.61µm was observed, 4.60µm above the original. They were analyzed using Stu- dent's t test; in both cases the result was p>0.05. When com- paring groups I and II, using the t-test and the Mann-Whitney nonparametric verification, non-significant differences were observed, p=0.41 and p=0.38 respectively. Conclusions: Under the conditions of this study, it was ob- served that the two welding methods analyzed were reliable for joining metallic superstructures without affecting their final fit (AU)

Chemical passivation as a method of improving the electrochemical corrosion resistance of Co-Cr-based dental alloy.

PURPOSE: The purpose of the study was to evaluate corrosion resistance of Wirobond C® alloy after chemical passivation treatment. METHODS: The alloy surface undergone chemical passivation treatment in four different media. Corrosion studies were carried out by means of electrochemical methods in saline solution. Corrosion effects were determined using SEM. RESULTS: The greatest increase in the alloy polarization resistance was observed for passive layer produced in Na2SO4 solution with graphite. The same layer caused the highest increase in corrosion current. Generally speaking, the alloy passivation in Na2SO4 solution with graphite caused a substantial improvement of the corrosion resistance. The sample after passivation in Na2SO4 solution without graphite, contrary to others, lost its protective properties along with successive anodic polarization cycles. The alloy passivation in Na3PO4 solution with graphite was the only one that caused a decrease in the alloy corrosion properties. The SEM studies of all samples after chemical passivation revealed no pit corrosion - in contrast to the sample without any modification. CONCLUSIONS: Every successive polarization cycle in anodic direction of pure Wirobond C® alloy enhances corrosion resistance shifting corrosion potential in the positive direction and decreasing corrosion current value. The chemical passivation in solutions with low pH values decreases susceptibility to electrochemical corrosion of Co-Cr dental alloy. The best protection against corrosion was obtained after chemical passivation of Wirobond C® in Na2SO4 solution with graphite. Passivation with Na2SO4 in solution of high pH does not cause an increase in corrosion resistance of WIROBOND C. Passivation process increases alloy resistance to pit corrosion.

Growth, mechanical, thermal and spectral properties of Cr3+:MgMoO4 crystal.

This paper reports the growth, mechanical, thermal and spectral properties of Cr(3+):MgMoO(4) crystals. The Cr(3+):MgMoO(4) crystals with dimensions up to 30 mm×18 mm×14 mm were obtained by TSSG method. The absorption cross-sections of (4)A(2)→(4)T(1) and (4)A(2)→(4)T(2) transitions are 12.94×10(-20) cm(2) at 493 nm and 7.89×10(-20) cm(2) at 705 nm for E//N(g), respectively. The Cr(3+):MgMoO(4) crystal shows broad band emission extending from 750 nm to 1300 nm with peak at about 705 nm. The emission cross-section with FWHM of 188 nm is 119.88×10(-20) cm(2) at 963 nm for E//N(g). The investigated results showed that the Cr(3+):MgMoO(4) crystal may be regarded as a potential tunable laser gain medium.

Mechanical alloying of biocompatible Co-28Cr-6Mo alloy.

We report on an alternative route for the synthesis of crystalline Co-28Cr-6Mo alloy, which could be used for surgical implants. Co, Cr and Mo elemental powders, mixed in an adequate weight relation according to ISO Standard 58342-4 (ISO, 1996), were used for the mechanical alloying (MA) of nano-structured Co-alloy. The process was carried out at room temperature in a shaker mixer mill using hardened steel balls and vials as milling media, with a 1:8 ball:powder weight ratio. Crystalline structure characterization of milled powders was carried out by X-ray diffraction in order to analyze the phase transformations as a function of milling time. The aim of this work was to evaluate the alloying mechanism involved in the mechanical alloying of Co-28Cr-6Mo alloy. The evolution of the phase transformations with milling time is reported for each mixture. Results showed that the resultant alloy is a Co-alpha solid solution, successfully obtained by mechanical alloying after a total of 10 h of milling time: first Cr and Mo are mechanically prealloyed for 7 h, and then Co is mixed in for 3 h. In addition, different methods of premixing were studied. The particle size of the powders is reduced with increasing milling time, reaching about 5 mum at 10 h; a longer time promotes the formation of aggregates. The morphology and crystal structure of milled powders as a function of milling time were analyzed by scanning electron microscopy and XR diffraction.

Polyethylene and cobalt-chromium molybdenium particles elicit a different immune response in vitro.

Periprosthetic osteolysis is a major clinical problem that limits the long-term survival of total joint arthroplasties. Particles of prosthetic material stimulate immune competent cells to release cytokines, which may cause bone loss and loosening of the prosthesis. This study examined the following hypothesis. Polyethylene and titanium particles elicit a different immune response in vitro. To test these hypotheses, we used the human bone marrow cell culture model that we have established and previously used to examine particle associated cytokine release. Ultra high molecular weight polyethylene (UHMW-PE) induced a proliferation of CD14 positive cells (monocytes/macrophages) whereas cobalt chromium molybdenium (CoCrMb) particles demonstrated an increased proliferation of CD66b positive cells (granulocytes). Light and scanning microscopic evaluation revealed that the UHMW-PE particles, which have built large clusters of particles (Ø7, 5 microm), were mainly surrounded by the cells and less phagocytosed. On the other hand the smaller particles from CoCrMb have been phagocytosed by the cells. These results provide strong support for our hypothesis: that wear particles derived from prosthetic materials of different material can elicit significantly different biologic responses. In summary the results suggest that the "in vitro" response to wear particles of different biomaterials should be investigated by culture systems of various lineages of cells.