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Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies.
Poineau, Frederic; Weck, Philippe F; German, Konstantin; Maruk, Alesya; Kirakosyan, Gayane; Lukens, Wayne; Rego, Daniel B; Sattelberger, Alfred P; Czerwinski, Kenneth R.
Affiliation
  • Poineau F; Department of Chemistry, University of Nevada Las Vegas, Las Vegas, NV 89154, USA. poineauf@unlv.nevada.edu
Dalton Trans ; 39(37): 8616-9, 2010 Oct 07.
Article in En | MEDLINE | ID: mdl-20730190
The speciation of Tc(vii) was studied in 12 M H(2)SO(4) by NMR, UV-visible and XAFS spectroscopy. Experimental results and density functional calculations show the formation of TcO(3)(OH)(H(2)O)(2).
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Sulfuric Acids / Technetium Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2010 Document type: Article Affiliation country: United States Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Sulfuric Acids / Technetium Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2010 Document type: Article Affiliation country: United States Country of publication: United kingdom