[2,6-Bis(6-methyl-quinolin-2-yl)pyridine-κN,N',N'']dichloridoiron(II).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 10): m1299, 2010 Sep 25.
Article
in En
| MEDLINE
| ID: mdl-21587438
In the mol-ecule of the title compound, [FeCl(2)(C(25)H(19)N(3))], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Fe(II) atom is 32% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.938â
(11):0.062â
(11) ratio. Inter-molecular C-Hâ¯Cl hydrogen bonding occurs in the crystal structure.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2010
Document type:
Article
Country of publication:
United States