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Crystal structure of 2-meth-oxy-2-[(4-meth-oxy-phen-yl)sulfan-yl]-1-phenyl-ethanone.
Caracelli, Ignez; Olivato, Paulo R; Traesel, Henrique J; Valença, Jéssica; Rodrigues, Daniel N S; Tiekink, Edward R T.
Affiliation
  • Caracelli I; Departmento de Física, Universidade Federal de São Carlos, 13565-905 São Carlos, SP, Brazil.
  • Olivato PR; Instituto de Química, Universidade de São Paulo, 05508-000 São Paulo, SP, Brazil.
  • Traesel HJ; Instituto de Química, Universidade de São Paulo, 05508-000 São Paulo, SP, Brazil.
  • Valença J; Instituto de Química, Universidade de São Paulo, 05508-000 São Paulo, SP, Brazil.
  • Rodrigues DN; Instituto de Química, Universidade de São Paulo, 05508-000 São Paulo, SP, Brazil.
  • Tiekink ER; Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Acta Crystallogr E Crystallogr Commun ; 71(Pt 9): o657-8, 2015 Sep 01.
Article in En | MEDLINE | ID: mdl-26396889
In the title ß-thio-carbonyl compound, C16H16O3S, the adjacent meth-oxy and carbonyl O atoms are synperiplanar [the O-C-C-O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the meth-oxy group is coplanar with the benzene ring to which it is connected [the C-C-O-C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C-H⋯O(carbon-yl) inter-actions that lead to a supra-molecular chain with a zigzag topology along the c axis. Chains pack with no specific inter-molecular inter-actions between them.
Key words

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Acta Crystallogr E Crystallogr Commun Year: 2015 Document type: Article Affiliation country: Brazil Country of publication: United kingdom

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Acta Crystallogr E Crystallogr Commun Year: 2015 Document type: Article Affiliation country: Brazil Country of publication: United kingdom