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Homochiral mononuclear Dy-Schiff base complexes showing field-induced double magnetic relaxation processes.
Ren, Min; Xu, Zhong-Li; Wang, Ting-Ting; Bao, Song-Song; Zheng, Ze-Hua; Zhang, Zai-Chao; Zheng, Li-Min.
Affiliation
  • Ren M; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China. lmzheng@nju.edu.cn.
  • Xu ZL; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China. lmzheng@nju.edu.cn.
  • Wang TT; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China. lmzheng@nju.edu.cn.
  • Bao SS; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China. lmzheng@nju.edu.cn.
  • Zheng ZH; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China. lmzheng@nju.edu.cn.
  • Zhang ZC; School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an 223300, China.
  • Zheng LM; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China. lmzheng@nju.edu.cn.
Dalton Trans ; 45(2): 690-5, 2016 Jan 14.
Article in En | MEDLINE | ID: mdl-26621766
A pair of enantiopure mononuclear dysprosium/salen-type complexes (Et3NH)[Dy((R,R)/(S,S)-3-NO2salcy)2] (/), where 3-NO2salcyH2 represents N,N'-(1,2-cyclohexanediylethylene)bis(3-nitrosalicylideneiminato), are reported. The enantiomer contains two crystallographically independent dysprosium(iii) ions, each chelated by two enantiopure 3-NO2salcy(2-) ligands forming a [DyN4O4] core. Detailed magnetic studies on compound reveal a field-induced dual magnetic relaxation behavior, originating from single ion anisotropy and intermolecular interactions, respectively.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2016 Document type: Article Affiliation country: China Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Journal subject: QUIMICA Year: 2016 Document type: Article Affiliation country: China Country of publication: United kingdom