Application of In-Line Mid-Infrared (MIR) Spectroscopy Coupled with Calorimetry for the Determination of the Molar Enthalpy of Reaction between Ammonium Chloride and Sodium Nitrite.

The reaction between ammonium chloride and sodium nitrite has been known for its application as a source of heat because of its large enthalpy of reaction, for which it has been used by the oil industry. There have been no known calorimetric studies for the experimental determination of its molar enthalpy of reaction, which is necessary in order to predict the limits achieved for up-scale applications. Attenuated total reflection Fourier transform infrared spectroscopy (ATR FT-IR) and reaction calorimetry were used to determine this value by using a simple methodology. Both techniques were used concomitantly as a source of information regarding the time-dependent moles converted (Δn) and the amount of exchanged heat (ΔH). The molar enthalpy of reaction was calculated to be -74 ± 4 kcal mol(-1). The percentage between the confidence interval and the calculated value was 5.4%, which shows that the methodology was precise. After the determination of the molar enthalpy of reaction, it was proved that the ATR FT-IR alone was able to be used as a substitute for the reaction calorimetry technique, in which the IR signal is converted to the heat information, presenting as an easier technique for the monitoring of the heat released by this system for future applications.