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Towards the total synthesis of keramaphidin B.
Jakubec, Pavol; Farley, Alistair J M; Dixon, Darren J.
Affiliation
  • Jakubec P; Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, United Kingdom.
  • Farley AJ; Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, United Kingdom.
  • Dixon DJ; Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, United Kingdom.
Beilstein J Org Chem ; 12: 1096-100, 2016.
Article in En | MEDLINE | ID: mdl-27340496
The enantio- and diastereoselective Michael addition of a δ-valerolactone-derived pronucleophile to a substituted furanyl nitroolefin catalysed by a bifunctional cinchonine-derived thiourea has been used as the key stereocontrolling step in a new synthetic strategy to the heavily functionalised piperidine core of keramaphidin B.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Beilstein J Org Chem Year: 2016 Document type: Article Affiliation country: United kingdom Country of publication: Germany
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Beilstein J Org Chem Year: 2016 Document type: Article Affiliation country: United kingdom Country of publication: Germany