Direct Experimental Characterization of a Bridged Bicyclic Glycosyl Dioxacarbenium Ion by <sup>1</sup> H and <sup>13</sup> CâNMR Spectroscopy: Importance of Conformation on Participation by Distal Esters.

Upadhyaya, Kapil; Subedi, Yagya P; Crich, David

Direct Experimental Characterization of a Bridged Bicyclic Glycosyl Dioxacarbenium Ion by ¹ H and ¹³ CâNMR Spectroscopy: Importance of Conformation on Participation by Distal Esters.

Upadhyaya, Kapil; Subedi, Yagya P; Crich, David.

Affiliation

Upadhyaya K; Department of Pharmaceutical and Biomedical Sciences, University of Georgia, 250 West Green Street, Athens, GA, 30602, USA.
Subedi YP; Department of Pharmaceutical and Biomedical Sciences, University of Georgia, 250 West Green Street, Athens, GA, 30602, USA.
Crich D; Department of Pharmaceutical and Biomedical Sciences, University of Georgia, 250 West Green Street, Athens, GA, 30602, USA.

Angew Chem Int Ed Engl ; 60(48): 25397-25403, 2021 11 22.

Article in En | MEDLINE | ID: mdl-34543505

Subject(s)

Bridged Bicyclo Compounds, Heterocyclic/chemistry; Esters/chemistry; Glycosides/chemistry; Carbohydrate Conformation; Carbon-13 Magnetic Resonance Spectroscopy; Glycosylation; Ions/chemistry; Proton Magnetic Resonance Spectroscopy; Stereoisomerism

Key words

dioxacarbenium ion; distal group participation; glycosylation; variable-temperature NMR

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Bridged Bicyclo Compounds, Heterocyclic / Esters / Glycosides Type of study: Prognostic_studies Language: En Journal: Angew Chem Int Ed Engl Year: 2021 Document type: Article Affiliation country: United States Country of publication: Germany

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