Construction of ZnxCdyS with a 3D Hierarchical Structure for Enhanced Photocatalytic Hydrogen Production from Water Splitting.

The ZnxCdyS has been proven to have unique photoelectric properties, but its synthesis method and photocatalytic water cracking performance need to be further improved. In this paper, Cd-MOF@ZIF-8 with a MOF-on-MOF (MOF = metal-organic framework) structure was prepared by a simple ion adsorption method. Then, a CdS/ZnxCdyS heterojunction with a 3D hierarchical structure was formed by solvothermal sulfidation. The prepared catalysts with different Zn/Cd ratios show an improved hydrogen production performance for photocatalytic water splitting, and the hydrogen evolution rate of Zn1Cd1S can reach up to 29.2 mmol·g-1·h-1. The excellent photocatalytic activity not only benefits from ZnxCdyS strong light conversion ability but also is closely related to the hierarchical structure and large specific surface area. A type II heterojunction also plays an important role in the spatial separation of photogenerated carriers. This paper provides a simple and feasible idea for the synthesis of a photocatalyst with a large specific surface area using a MOF-on-MOF synthesis strategy.