Leaching Vanadium from the Spent Denitration Catalyst in the Sulfuric Acid/Oxalic Acid Combined Solvent.

ABSTRACT

Huge amounts of spent denitration catalysts are produced annually as waste from the flue gas denitration process, which will cause resource waste and environmental pollution. It is important to develop an efficient method for the recovery of metals from spent denitration catalysts. In this work, the leaching of vanadium (V) from the spent denitration catalyst by the sulfuric acid/oxalic acid combined solvent was investigated. Factors that influence the leaching rate of V have been studied. Results showed that the optimal leaching rate was 95.65% by 20 wt % sulfuric acid and 0.3 mol·L-1 oxalic acid with a liquid-to-solid ratio of 20 mL·g-1 at 140 °C for 7 h. For further study of the leaching process, the leaching mechanism of V was explored subsequently. Results indicated that sulfuric acid provided a strongly acidic environment, which was beneficial to transformation, complexation, and redox reactions of V in the mixed acid leaching system. Meanwhile, oxalic acid with excellent complexation and reducing-dissolving properties promoted the formation of stable water-soluble VO2+. The "complex effect" generated from the combined acids was greatly favored for leaching V from the spent denitration catalyst.