Bis{(S)-(-)-N-[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κN}di-chlorido-palladium(II).
IUCrdata
; 9(Pt 7): x240555, 2024 Jul.
Article
in En
| MEDLINE
| ID: mdl-39108936
ABSTRACT
The PdII complex bis-{(S)-(-)-N-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κN}di-chlorido-palladium(II), [PdCl2(C22H21NO)2], crystallizes in the monoclinic Sohncke space group P21 with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85â
(19), 88.10â
(17), 89.96â
(18), and 90.0â
(2)°, while the Pd-Cl and Pd-N bond lengths are 2.310â
(2) and 2.315â
(2)â
Å and 2.015â
(2) and 2.022â
(6)â
Å, respectively. The crystal structure features inter-molecular N-Hâ¯Cl and intramolecular C-Hâ¯Pd inter-actions, which lead to the formation of a supramolecular framework structure.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
IUCrdata
Year:
2024
Document type:
Article
Affiliation country:
Mexico
Country of publication:
United kingdom