Multieffect Preoxidation Strategy to Convert Bituminous Coal into Hard Carbon for Enhancing Sodium Storage Performance.
ACS Appl Mater Interfaces
; 16(35): 46226-46236, 2024 Sep 04.
Article
in En
| MEDLINE
| ID: mdl-39172642
ABSTRACT
Preoxidation is an effective strategy to inhibit the graphitization of coals during carbonization. However, the single effect of the traditional preoxidation strategy could barely increase surface-active sites, hindering further enhancement of sodium storage. Herein, a multieffect preoxidation strategy was proposed to suppress structural rearrangement and create abundant surface-active sites. Mg(NO3)2·6H2O helps to introduce oxygen-containing functional groups into bituminous coal at 450 °C, which acted as a cross-linking agent to inhibit the rearrangement of carbon layers and promote structural cross-linking during the subsequent thermal carbonization process. Besides, the residue solid decomposition product MgO would react with carbon to create surface-active sites. The obtained coal-based hard carbon contained more pseudographitic domains and sodium storage active sites. The optimized sample could deliver an excellent capacity of 287.1 mAh g-1 at 20 mA g-1, as well as remarkable cycling stability of capacity retention of 96.1% after 200 cycles at 50 mA g-1, and notable capacity retention of 88.9% after 1000 cycles at 300 mA g-1. This work provides an effective and practical strategy to convert low-cost bituminous coal into advanced hard carbon anodes for sodium-ion batteries (SIBs).
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
ACS Appl Mater Interfaces
/
ACS appl. mater. interfaces (Online)
/
ACS applied materials & interfaces (Online)
Journal subject:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Year:
2024
Document type:
Article
Country of publication:
United States