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Attosecond impulsive stimulated X-ray Raman scattering in liquid water.
Alexander, Oliver; Egun, Felix; Rego, Laura; Gutierrez, Ana Martinez; Garratt, Douglas; Cardenes, Gustavo Adolfo; Nogueira, Juan J; Lee, Jacob P; Zhao, Kaixiang; Wang, Ru-Pan; Ayuso, David; Barnard, Jonathan C T; Beauvarlet, Sandra; Bucksbaum, Philip H; Cesar, David; Coffee, Ryan; Duris, Joseph; Frasinski, Leszek J; Huse, Nils; Kowalczyk, Katarzyna M; Larsen, Kirk A; Matthews, Mary; Mukamel, Shaul; O'Neal, Jordan T; Penfold, Thomas; Thierstein, Emily; Tisch, John W G; Turner, James R; Vogwell, Josh; Driver, Taran; Berrah, Nora; Lin, Ming-Fu; Dakovski, Georgi L; Moeller, Stefan P; Cryan, James P; Marinelli, Agostino; Picón, Antonio; Marangos, Jonathan P.
Affiliation
  • Alexander O; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Egun F; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Rego L; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Gutierrez AM; Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nano), Cantoblanco, 28049 Madrid, Spain.
  • Garratt D; Departamento de Química, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
  • Cardenes GA; Departamento de Química, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
  • Nogueira JJ; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Lee JP; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Zhao K; Departamento de Química, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
  • Wang RP; Departamento de Química, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
  • Ayuso D; Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain.
  • Barnard JCT; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Beauvarlet S; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Bucksbaum PH; Center for Free-Electron Laser Science, Department of Physics, University of Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany.
  • Cesar D; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Coffee R; Max-Born-Institut, Max-Born-Str. 2A, 12489 Berlin, Germany.
  • Duris J; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Frasinski LJ; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Huse N; Physics department, University of Connecticut, Storrs, CT 06268, USA.
  • Kowalczyk KM; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Larsen KA; Department of Applied Physics, Stanford University, Stanford, CA, USA.
  • Matthews M; Department of Physics, Stanford University, Stanford, CA, USA.
  • Mukamel S; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • O'Neal JT; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Penfold T; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Thierstein E; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Tisch JWG; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Turner JR; Center for Free-Electron Laser Science, Department of Physics, University of Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany.
  • Vogwell J; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Driver T; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Berrah N; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Lin MF; Department of Physics, Imperial College London, Blackett Laboratory, SW7 2AZ London, UK.
  • Dakovski GL; Departments of Chemistry and Physics and Astronomy, University of California-Irvine, Irvine, CA 92697, USA.
  • Moeller SP; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Cryan JP; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Marinelli A; Chemistry-School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne NE1 7RU, UK.
  • Picón A; SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Marangos JP; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
Sci Adv ; 10(39): eadp0841, 2024 Sep 27.
Article in En | MEDLINE | ID: mdl-39321305
ABSTRACT
We report the measurement of impulsive stimulated x-ray Raman scattering in neutral liquid water. An attosecond pulse drives the excitations of an electronic wavepacket in water molecules. The process comprises two

steps:

a transition to core-excited states near the oxygen atoms accompanied by transition to valence-excited states. Thus, the wavepacket is impulsively created at a specific atomic site within a few hundred attoseconds through a nonlinear interaction between the water and the x-ray pulse. We observe this nonlinear signature in an intensity-dependent Stokes Raman sideband at 526 eV. Our measurements are supported by our state-of-the-art calculations based on the polarization response of water dimers in bulk solvation and propagation of attosecond x-ray pulses at liquid density.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Sci Adv Year: 2024 Document type: Article Affiliation country: United kingdom Country of publication: United States
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Sci Adv Year: 2024 Document type: Article Affiliation country: United kingdom Country of publication: United States