µ-2,3,5,6-Tetra-2-pyridylpyrazine-κN,N,N:κN,N,N-bis-[(methanol-κO)(nitrato-κO,O')(nitrato-κO)cadmium(II)].
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 8): m1050-1, 2008 Jul 19.
Article
en En
| MEDLINE
| ID: mdl-21203037
The title complex, [Cd(2)(NO(3))(4)(C(24)H(16)N(6))(CH(4)O)(2)], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra-2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323â
(4)â
Å. Each Cd(II) center is seven-coordinated by three N-atom donors of tppz in one plane, by two O atoms nearly normal to this plane, and by two O atoms 0.393â
(3) and 0.488â
(3)â
Å from that plane. The two Cd(II) ions are above and below the plane of the pyrazine ring of the tppz ligand, oriented with respect to the pyridine rings at dihedral angles of 38.01â
(3) and 31.90â
(3)°. The dihedral angle between the two pyridine rings is 41.11â
(3)°. In the crystal structure, inter-molecular O-Hâ¯O hydrogen bonds link the mol-ecules.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2008
Tipo del documento:
Article
Pais de publicación:
Estados Unidos