Interception of a Rh(I)-Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph-BPE}].
Dalton Trans
; 41(12): 3369-73, 2012 Mar 28.
Article
en En
| MEDLINE
| ID: mdl-22344474
ABSTRACT
Reaction of [Rh(CO)(2){(R,R)-Ph-BPE}][BF(4)] 1 under 7 bar H(2) provides the dihydride [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}][BF(4)] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph-BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh((I))-Rh((III)) complex [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}][BF(4)] 4.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Asunto de la revista:
QUIMICA
Año:
2012
Tipo del documento:
Article
País de afiliación:
Francia