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C8-H bond activation vs. C2-H bond activation: from naphthyl amines to lactams.
Shi, Renyi; Lu, Lijun; Xie, Hangyu; Yan, Jingwen; Xu, Ting; Zhang, Hua; Qi, Xiaotian; Lan, Yu; Lei, Aiwen.
Afiliación
  • Shi R; College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China. aiwenlei@whu.edu.cn.
  • Lu L; College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China. aiwenlei@whu.edu.cn.
  • Xie H; College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China. aiwenlei@whu.edu.cn.
  • Yan J; College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China. aiwenlei@whu.edu.cn.
  • Xu T; School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, P. R. China. lanyu@cqu.edu.cn.
  • Zhang H; College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China. aiwenlei@whu.edu.cn.
  • Qi X; School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, P. R. China. lanyu@cqu.edu.cn.
  • Lan Y; School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, P. R. China. lanyu@cqu.edu.cn.
  • Lei A; College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China. aiwenlei@whu.edu.cn and State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000,
Chem Commun (Camb) ; 52(90): 13307-13310, 2016 Nov 03.
Article en En | MEDLINE | ID: mdl-27782272
Pd-catalyzed selective amine-oriented C8-H bond functionalization/N-dealkylative carbonylation of naphthyl amines has been achieved. The amine group from dealkylation is proposed to be the directing group for promoting this process. It represents a straightforward and easy method to access various biologically important benzo[cd]indol-2(1H)-one derivatives.
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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article Pais de publicación: Reino Unido
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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article Pais de publicación: Reino Unido