Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes.
Chem Commun (Camb)
; 53(56): 7894-7897, 2017 Jul 11.
Article
en En
| MEDLINE
| ID: mdl-28480906
ABSTRACT
Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 °C and 5 bar H2 pressure), providing excellent activities and selectivities.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2017
Tipo del documento:
Article
País de afiliación:
España