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Ring-Opening Copolymerization of Maleic Anhydride with Functional Epoxides: Poly(propylene fumarate) Analogues Capable of Post-Polymerization Modification.
Chen, Yusheng; Wilson, James A; Petersen, Shannon R; Luong, Derek; Sallam, Sahar; Mao, Jialin; Wesdemiotis, Chrys; Becker, Matthew L.
Afiliación
  • Chen Y; Department of Polymer Science, The University of Akron, Akron, OH, 44325, USA.
  • Wilson JA; Department of Polymer Science, The University of Akron, Akron, OH, 44325, USA.
  • Petersen SR; Department of Polymer Science, The University of Akron, Akron, OH, 44325, USA.
  • Luong D; Department of Polymer Science, The University of Akron, Akron, OH, 44325, USA.
  • Sallam S; Department of Chemistry, The University of Akron, Akron, OH, 44325, USA.
  • Mao J; Department of Chemistry, The University of Akron, Akron, OH, 44325, USA.
  • Wesdemiotis C; Department of Polymer Science, The University of Akron, Akron, OH, 44325, USA.
  • Becker ML; Department of Chemistry, The University of Akron, Akron, OH, 44325, USA.
Angew Chem Int Ed Engl ; 57(39): 12759-12764, 2018 09 24.
Article en En | MEDLINE | ID: mdl-30080946
ABSTRACT
Three functional epoxides were copolymerized with maleic anhydride to yield degradable poly(propylene fumarate) analogues. The polymers were modified post-polymerization and post-printing with either click-type addition reactions or UV deprotection to either attach bioactive species or increase the hydrophilicity. Successful dye attachment, induced wettability, and improved cell spreading show the viability of these analogues in biomaterials applications.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polipropilenos / Compuestos Epoxi / Fumaratos / Anhídridos Maleicos Límite: Animals Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polipropilenos / Compuestos Epoxi / Fumaratos / Anhídridos Maleicos Límite: Animals Idioma: En Revista: Angew Chem Int Ed Engl Año: 2018 Tipo del documento: Article País de afiliación: Estados Unidos