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Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,ß-unsaturated aldehydes.
Liang, Zuyu; Chen, Jianbin; Chen, Xin; Zhang, Kai; Lv, Jinhe; Zhao, Haowen; Zhang, Guoying; Xie, Congxia; Zong, Lingbo; Jia, Xiaofei.
Afiliación
  • Liang Z; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Chen J; Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, P. R. China.
  • Chen X; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Zhang K; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Lv J; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Zhao H; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Zhang G; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Xie C; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Zong L; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
  • Jia X; Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. jiaxiaofei139@163.com lingbozong@qust.edu.cn.
Chem Commun (Camb) ; 55(91): 13721-13724, 2019 Nov 25.
Article en En | MEDLINE | ID: mdl-31658306
A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh3) has been developed for the hydroformylation of various alkynes to afford the corresponding α,ß-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh3 system.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2019 Tipo del documento: Article Pais de publicación: Reino Unido