Infrared + vacuum ultraviolet two-color ionization spectroscopy of neutral metal complexes based on a tunable vacuum ultraviolet free-electron laser.
Rev Sci Instrum
; 91(3): 034103, 2020 Mar 01.
Article
en En
| MEDLINE
| ID: mdl-32259935
This paper describes an experimental technique for studying neutral metal complexes using infrared + vacuum ultraviolet (IR+VUV) two-color ionization spectroscopy based on a tunable VUV free-electron laser (VUV-FEL). The preliminary IR spectroscopy results of mass-selected nickel tetracarbonyl are reported in this work. The results demonstrate that the tunable VUV-FEL light allows the selective ionization of a given neutral cluster free of confinement along with the recording of well-resolved IR spectra. As the ionization energies of many neutral clusters are accessible by a broadly tunable VUV-FEL (50-150 nm) and near-threshold ionization can be readily achieved, the proposed experimental method offers unique possibilities for the size-specific study of a wide variety of confinement-free neutral clusters.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Rev Sci Instrum
Año:
2020
Tipo del documento:
Article
País de afiliación:
China
Pais de publicación:
Estados Unidos