Your browser doesn't support javascript.
loading
Selective oxidative ß-C-H bond sulfenylation of tetrahydroisoquinolines with elemental sulfur.
Guo, Tao; Bi, Lei; Shen, Lu; Wei, Quanhong; Zhu, Congjun; Zhang, Panke; Zhao, Yunhui.
Afiliación
  • Guo T; School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, Henan 450001, P. R. China. CongjunZhu@haut.edu.cn.
  • Bi L; School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, Henan 450001, P. R. China. CongjunZhu@haut.edu.cn.
  • Shen L; School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, Henan 450001, P. R. China. CongjunZhu@haut.edu.cn.
  • Wei Q; School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, Henan 450001, P. R. China. CongjunZhu@haut.edu.cn.
  • Zhu C; School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou, Henan 450001, P. R. China. CongjunZhu@haut.edu.cn.
  • Zhang P; Green Catalysis Center, College of Chemistry, Henan Advanced Institute of Technology, Zhengzhou University, Zhengzhou 450001, PR China. pkzhang@zzu.edu.cn.
  • Zhao Y; School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, P. R. China. zhao_yunhui@163.com.
Org Biomol Chem ; 21(1): 127-131, 2022 12 21.
Article en En | MEDLINE | ID: mdl-36484417
In this article, a convenient and efficient KIO3-promoted oxidative sulfenylation at the ß-position of tetrahydroisoquinolines and subsequent aromatization in the presence of elemental S8 is presented. The reaction proceeds with moderate to good yields via a double C-S formation process. A wide range of structurally diverse 4-sulfenylisoquinolines/3-sulfenylpiperidine were synthesized with excellent functional group tolerance and high efficiency.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Tetrahidroisoquinolinas Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Tetrahidroisoquinolinas Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2022 Tipo del documento: Article Pais de publicación: Reino Unido