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Nickel-catalyzed stereoselective reductive cross-coupling of gem-difluoroalkenes with alkenyl electrophiles.
Li, Xiaowei; Li, Yuxiu; Shan, Wenlong; Wang, Zemin; Liu, Ruihua; Zhang, Zhong; Li, Xiangqian; Shi, Dayong.
Afiliación
  • Li X; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
  • Li Y; School of Chemistry and Environment, Jiaying University, Meizhou 514015, Guangdong, P. R. China.
  • Shan W; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
  • Wang Z; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
  • Liu R; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
  • Zhang Z; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
  • Li X; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
  • Shi D; State Key Laboratory of Microbial Technology, Shandong University, 72 Binhai Road, Qingdao 266237, Shandong, P. R. China. shidayong@sdu.edu.cn.
Chem Commun (Camb) ; 59(45): 6893-6896, 2023 Jun 01.
Article en En | MEDLINE | ID: mdl-37199088
Herein we develop a Ni-catalyzed defluorinative cross-electrophile coupling of gem-difluoroalkenes with alkenyl electrophiles that allowed the generation of C(sp2)-C(sp2) bonds. The reaction provided various monofluoro 1,3-dienes with broad functional group compatibility and excellent stereoselectivity. Synthetic transformations and applications to the modification of complex compounds were also demonstrated.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article Pais de publicación: Reino Unido
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article Pais de publicación: Reino Unido