Transition-Metal-Catalyzed Directed C-H Functionalization in/on Water.

Shah, Tariq A; Sarkar, Tanumay; Kar, Subhradeep; Maharana, Prabhat Kumar; Talukdar, Kangkan; Punniyamurthy, Tharmalingam

Shah, Tariq A; Sarkar, Tanumay; Kar, Subhradeep; Maharana, Prabhat Kumar; Talukdar, Kangkan; Punniyamurthy, Tharmalingam.

Afiliación

Shah TA; Department of Chemistry and Advanced Material Chemistry Center (AMCC), Khalifa University, PO Box, 127788, Abu Dhabi, U.A.E.
Sarkar T; Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781039, India.
Kar S; Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781039, India.
Maharana PK; Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781039, India.
Talukdar K; Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781039, India.
Punniyamurthy T; Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781039, India.

Chem Asian J ; 19(1): e202300815, 2024 Jan 02.

Article en En | MEDLINE | ID: mdl-37932013

ABSTRACT

ABSTRACT

Directing group assisted C-H bond functionalization using transition-metal-catalysis has emerged as a reliable synthetic tool for the construction of regioselective carbon-carbon/heteroatom bonds. Off late, "in/on water directed transition-metal-catalysis", though still underdeveloped, has appeared as one of the prominent themes in sustainable organic chemistry. This article covers the advancements, mechanistic insights and application of the sustainable directed C-H bond functionalization of (hetero)arenes in/on water in the presence of transition-metal-catalysis.

Palabras clave

Directing group; Site-selective C−H Functionalization; reaction in/on water; transition-metal-catalysis

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Asian J Año: 2024 Tipo del documento: Article