Synthesis of 1,1'-Bicarbazoles by Sequential Iron(III)- and Palladium(II)-Catalyzed Oxidative Coupling Reactions.
Chemistry
; 30(18): e202303794, 2024 Mar 25.
Article
en En
| MEDLINE
| ID: mdl-38269422
ABSTRACT
The iron(III)-catalyzed oxidative coupling of diarylamines to 2,2'-bis(arylamino)-1,1'-biaryls and subsequent twofold palladium(II)-catalyzed oxidative cyclization provide a convergent synthetic route to 1,1'-bicarbazoles. Screening a range of different palladium(II) salts led to palladium(II) acetate, pivalate, and hexafluoroacetylacetonate as the most efficient catalysts. Remarkably, the twofold palladium(II)-catalyzed oxidative cyclization can also be performed under argon. The mechanism for the oxidative cyclization under an inert gas presumably involves regeneration of the catalytically active palladium(II) species by oxidative addition of pivalic acid.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2024
Tipo del documento:
Article
País de afiliación:
Alemania
Pais de publicación:
Alemania