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Three-dimensional ordered macroporous LaFe1-xMnxO3 with high stability for efficient NO oxidation and sulfur resistance.
Zuo, Shengjie; Wang, Ping; He, Miao; Yao, Jiasai; Li, Haocheng; Xiong, Jing; Sun, Xiaohua; Wei, Yuechang; Li, Zhenxing.
Afiliación
  • Zuo S; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
  • Wang P; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
  • He M; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
  • Yao J; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
  • Li H; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
  • Xiong J; College of Science, China University of Petroleum (Beijing), Beijing 102249, China. weiyc@cup.edu.cn.
  • Sun X; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
  • Wei Y; College of Science, China University of Petroleum (Beijing), Beijing 102249, China. weiyc@cup.edu.cn.
  • Li Z; State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China. lizx@cup.edu.cn.
Chem Commun (Camb) ; 60(39): 5157-5160, 2024 May 09.
Article en En | MEDLINE | ID: mdl-38639479
ABSTRACT
NOx is an air pollutant that affects human health. A series of perovskite catalysts with different ratios of lanthanum, iron, and manganese and a three-dimensional ordered microporous structure was prepared, and the strongest catalytic performance was obtained with the LaFe0.1Mn0.9O3 catalyst. LaFe0.1Mn0.9O3 possesses the greatest number of oxygen vacancies and reached 77% NO oxidation conversion at 250 °C, with the highest NO oxidation conversion of 99% at 318 °C. This work provides a promising non-precious metal catalyst for NO oxidation and soot combustion.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido