Generation and study of Am(IV) by temperature-controlled electron pulse radiolysis.

Kynman, Amy E; Grimes, Travis S; Mezyk, Stephen P; Layne, Bobby; Cook, Andrew R; Rotermund, Brian M; Horne, Gregory P

Kynman, Amy E; Grimes, Travis S; Mezyk, Stephen P; Layne, Bobby; Cook, Andrew R; Rotermund, Brian M; Horne, Gregory P.

Afiliación

Kynman AE; Center for Radiation Chemistry Research, Idaho National Laboratory, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov.
Grimes TS; Glenn T. Seaborg Institute, Idaho National Laboratory, Idaho Falls, ID, 83415, USA. amy.kynman@inl.gov.
Mezyk SP; Center for Radiation Chemistry Research, Idaho National Laboratory, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov.
Layne B; Department of Chemistry and Biochemistry, California State University Long Beach, Long Beach, CA 90840, USA.
Cook AR; Department of Chemistry, Brookhaven National Laboratory, Upton, New York, 11973, USA.
Rotermund BM; Department of Chemistry, Brookhaven National Laboratory, Upton, New York, 11973, USA.
Horne GP; Department of Chemistry, Colorado School of Mines, Golden, Colorado 80401, USA.

Dalton Trans ; 53(22): 9262-9266, 2024 Jun 04.

Article en En | MEDLINE | ID: mdl-38776119

ABSTRACT

ABSTRACT

First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(IV) in concentrated (6.0 M) HNO3, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO3Ë and Am(III).

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

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