Palladium/norbornene-catalyzed C-H/N-H cycloaddition of carbazoles with 2-halobenzoic acid derivatives.

Liu, Shilei; Nan, Jiang; An, Nan; Cao, Rui; Zhu, Lanxin; Yan, Qiang; Zhang, Hanqing; Liang, Chengyuan

Liu, Shilei; Nan, Jiang; An, Nan; Cao, Rui; Zhu, Lanxin; Yan, Qiang; Zhang, Hanqing; Liang, Chengyuan.

Afiliación

Liu S; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
Nan J; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
An N; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
Cao R; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
Zhu L; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
Yan Q; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
Zhang H; Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China. nanjiang@sust.edu.cn.
Liang C; Xi'an Key Laboratory of Antiviral and Antimicrobial-Resistant Bacteria Therapeutics Research, Xi'an, 710021, China.

Chem Commun (Camb) ; 2024 Sep 25.

Article en En | MEDLINE | ID: mdl-39319436

ABSTRACT

ABSTRACT

An example of palladium/norbornene-catalyzed C-H/N-H cycloaddition of carbazoles with 2-bromobenzoic acids is presented, in which a collection of important carbazoles is expeditiously obtained. Derivatives, including acyl halides, α-oxocarboxylic acids, anhydrides, and even amides, are all allowed. Preliminary mechanistic studies reveal that a rare six-membered spiropalladacycle is involved.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China Pais de publicación: Reino Unido

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