C/Co3O4/Diatomite Composite for Microwave Absorption.

ABSTRACT

Transition metal oxides have been widely used in microwave-absorbing materials, but how to improve impedance matching is still an urgent problem. Therefore, we introduced urea as a polymer carbon source into a three-dimensional porous structure modified by Co3O4 nanoparticles and explored the influence of different heat treatment temperatures on the wave absorption properties of the composite. The nanomaterials, when calcined at a temperature of 450 °C, exhibited excellent microwave absorption capabilities. Specifically, at an optimized thickness of 9 mm, they achieved a minimum reflection loss (RLmin) of -97.3 dB, accompanied by an effective absorption bandwidth (EAB) of 9.83 GHz that comprehensively covered both the S and Ku frequency bands. On the other hand, with a thickness of 3 mm, the RLmin was recorded as -17.9 dB, with an EAB of 5.53 GHz. This excellent performance is attributed to the multi-facial polarization and multiple reflections induced by the magnetic loss capability of Co3O4 nanoparticles, the electrical conductivity of C, and the unique three-dimensional structure of diatomite. For the future development of bio-based microwave absorption, this work provides a methodology and strategy.