Supramolecular Spin Chains via Radical-Radical Contacts Stabilizing Ferromagnetic Interactions between Heisenberg or Ising-like Spins.

ABSTRACT

A new paramagnetic ligand, 4-(2'-4-(2''-furyl)-pyrimidyl)-1,2,3,5-dithiadiazolyl (furylpymDTDA) and three transition metal coordination complexes, M(hfac)2(furylpymDTDA) M = Mn, Co, Ni; hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-), are reported. The solid-state structures are influenced by the geometry of the coordination sphere of the M(II) centers trigonal (Mn) vs. octahedral (Co and Ni). While the hs-Mn(II) complex exhibits pairwise multi-centre 2-electron bonds (i.e., pancake bonds) between the planar π radical DTDA moieties, the hs-Co(II) and Ni(II) complexes crystallize with close contacts between coordinated furylpymDTDA radical ligands that define linear 1D arrays of molecular units. The magnetic data for the hs-Co(II) and Ni(II) complexes indicate ferromagnetic (FM) interactions between molecular units, apparently mediated by radical-radical contacts along the supramolecular chains. Computational analysis suggests proximity between regions of large α- and ß-spin density on neighbouring molecular sites enabling FM exchange, in accordance with the McConnell I mechanism. The magnetic data for the Ni(II) complex are consistent with a Heisenberg spin chain, whereas the hs-Co(II) complex exhibits Ising-like spin chain behaviour and a magnetic phase transition to an FM ordered state at 4.6 K.