A Porphyrin-Phenylalkynyl-Based Conjugated Organic Polymer as a High-Performance Cathode for Rechargeable Organic Batteries.

ABSTRACT

Organic electrode materials (OEMs) have attracted much attention for rechargeable batteries due to their low cost, environment friendliness, flexibility, and structural versatility. Despite the above advantages, high solubility in electrolyte and low electronic conductivity remain critical limitations for the application of OEMs. In this work, the conjugated organic polymer (COP) poly([5,10,15,20-tetrakis(4-phenylalkynyl)porphyrin]Cu(II)) (PCuTPEP) is proposed as a cathode for high performance in organic lithium batteries. The polymerization inhibits the dissolution of the organic electrodes in the electrolyte, and the porphyrin and ethynyl-phenyl groups greatly expand the conjugated system and result in a high average discharge plateau at 4.0 V (vs Li+/Li). The PCuTPEP cathode exhibits a reversible discharge capacity of 119 mAh g-1 at a current of 50 mA g-1. Even at a high current density of 2.0 A g-1, excellent cycling stability up to 1000 cycles is achieved with capacity retentions of 88.5 and 90.4% at operating temperatures of 25 and 50 °C in organic lithium batteries, respectively. This study provides the approach for the development of organic cathodes for electrochemical energy storage.