Slow Magnetic Relaxation in a Lanthanide-[1]Metallocenophane Complex.

Latendresse, Trevor P; Bhuvanesh, Nattamai S; Nippe, Michael

Latendresse, Trevor P; Bhuvanesh, Nattamai S; Nippe, Michael.

Afiliação

Latendresse TP; Department of Chemistry, Texas A&M University , 3255 TAMU, College Station, Texas 77843, United States.
Bhuvanesh NS; Department of Chemistry, Texas A&M University , 3255 TAMU, College Station, Texas 77843, United States.
Nippe M; Department of Chemistry, Texas A&M University , 3255 TAMU, College Station, Texas 77843, United States.

J Am Chem Soc ; 139(24): 8058-8061, 2017 06 21.

Article em En | MEDLINE | ID: mdl-28590123

RESUMO

The first example of a lanthanide metallocenophane complex has been isolated as [Li(THF)4][DyFc3Li2(THF)2] (1). The molecular structure of complex 1 differs dramatically from those of main group and transition metal ferrocenophane complexes and features a distorted trigonal prismatic geometry around the Dy(III) ion and close intramolecular Dy···Fe distances. Furthermore, complex 1 exhibits all characteristics of a soft single-molecule magnet.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Estados Unidos País de publicação: Estados Unidos

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