Formation of Well-Defined Vesicles by Styrene Addition to a Nonionic Surfactant and Their Polymerization Leading to Viscous Hybrid Systems.

ABSTRACT

Self-assembled structures in aqueous solutions can be fixed by polymerization after adding hydrophobic monomers and can thereby be used as templates which allow to substantially alter the properties of these systems. In this work, we started from a self-assembled micellar system consisting of the nonionic surfactants tetradecyldimethylamine oxid and Pluronic L35 to which styrene was added as a polymerizable monomer. Interestingly, it was observed that styrene induces a transition from micelles to well-defined vesicles in a similar manner as a typical cosurfactant. The structural transition of the aggregates upon styrene addition as well as the structures formed after initiating a polymerization reaction were investigated by means of turbidity, dynamic and static light scattering, small-angle neutron scattering, and rheology measurements. Especially the scattering results confirmed the interesting effect of styrene on the mesoscopic structure and showed a structural evolution from rod-like micelles for low styrene concentrations to vesicles at intermediate styrene amounts, and then finally the formation of microemulsion droplets for high styrene content. Their polymerization of the vesicles again leads to a shape change to wormlike, polymerized aggregates, whose presence then results in rather viscous systems. In contrast, the microemulsions with higher styrene content then are templated and retain their size after polymerization, thereby leading to nanolattices.