A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts.
Beilstein J Org Chem
; 14: 2999-3010, 2018.
Article
em En
| MEDLINE
| ID: mdl-30591823
Stereoretentive olefin metathesis based on ruthenium dithiolate complexes has become a very active field of research within the past years. This unique catalyst class is able to kinetically produce both Z- and E-alkenes in high stereochemical purity (typically >95:5) starting from stereochemically pure Z- or E-alkenes. The aim of this tutorial review is to organize the reported information concerning ruthenium dithiolate catalysts in a logic manner, thus providing an "operators handbook" for chemists who wish to apply this methodology in synthesis.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Beilstein J Org Chem
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
França
País de publicação:
Alemanha