Thermodynamic stability of cis-azobenzene containing DNA materials based on van der Waals forces.
Chem Commun (Camb)
; 58(23): 3811-3814, 2022 Mar 18.
Article
em En
| MEDLINE
| ID: mdl-35234239
Taking advantage of van der Waals forces, an azobenzene-containing surfactant with a stable cis-state was designed and synthesized to fabricate photoresponsive DNA material. The reported DNA material exhibited reversible liquid crystalline-to-isotropic liquid transition under UV/Vis illuminations via the trans-cis isomerization of azobenzene. It also gained the ability to maintain the isotropic liquid state after UV light had ceased thanks to the thermodynamic stability of the cis-isomer of the azobenzene-containing surfactant. This work provides a design strategy for fabricating photoresponsive phase-change biomaterials.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Azo
/
DNA
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
China
País de publicação:
Reino Unido