Water-oil dual-channels enabled exceptional anti-fouling performances for separation of emulsified oil pollutant.

Oil contamination has been an increasingly concerned environmental issue due to the large quantity of oily wastewater discharged by the industry. The extreme wettability-enabled single-channel separation strategy guarantees efficient separation of oil pollutant from wastewater. However, the ultra-high selective permeability forces the intercepted oil pollutant to form a blocking layer, which weakens the separation capability and slows the kinetics of permeable phase. As a consequence, the single-channel separation strategy fails to maintain a stable flux for a long-term separation process. Herein, we reported a brand-new water-oil dual-channels strategy for accomplishing an ultra-stable long-term separation of emulsified oil pollutant from oil-in-water nano-emulsion by engineering two drastically opposite extreme wettabilities (i.e. superhydrophilicity and superhydrophobicity) to build the water-oil dual-channels. The strategy established the superwetting transport channels to permit water and oil pollutant to permeate through their own channel. In this way, the generation of intercepted oil pollutant was prevented, which guaranteed an exceptional long-lasting (20 h) anti-fouling performance for successful achievement of an ultra-stable separation of oil contamination from oil-in-water nano-emulsion with high flux retention and high separation efficiency. Therefore, our investigations provided a new route for realizing ultra-stable long-term separation of emulsified oil pollutant from wastewater.