Dinuclear ytterbium(III) benzamidinate complexes with bridging S32-, Se22- and Te22- ligands: synthesis, structure and magnetic properties.

Ma, Ying-Zhao; Yu, Lian; Zhou, Qi; Fu, Wensheng

Dinuclear ytterbium(III) benzamidinate complexes with bridging S₃^2-, Se₂^2- and Te₂^2- ligands: synthesis, structure and magnetic properties.

Ma, Ying-Zhao; Yu, Lian; Zhou, Qi; Fu, Wensheng.

Afiliação

Ma YZ; Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China. yzma@cqnu.edu.cn.
Yu L; Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China. yzma@cqnu.edu.cn.
Zhou Q; Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China. yzma@cqnu.edu.cn.
Fu W; Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China. yzma@cqnu.edu.cn.

Dalton Trans ; 53(19): 8118-8123, 2024 May 14.

Article em En | MEDLINE | ID: mdl-38690725

ABSTRACT

ABSTRACT

Treatment of Yb(II) complex [L2Yb(THF)2] (L = PhC(NSiMe3)2) with elemental sulfur, selenium or tellurium resulted in the isolation of a series of dinuclear Yb(III) complexes featuring side-on bound S32- (1), Se22- (2) or Te22- (3) moieties, respectively. Magnetic study on these complexes revealed that 3 is a rare lanthanide telluride single-molecule magnet (SMM).

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans / Dalton trans (2003. Online) / Dalton transactions (2003. Online) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China País de publicação: Reino Unido

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