Biomass-derived multiatom-doped carbon dots for water sensing based on excited state intraparticle proton transfer in organic solvents.
Spectrochim Acta A Mol Biomol Spectrosc
; 323: 124841, 2024 Dec 15.
Article
em En
| MEDLINE
| ID: mdl-39089070
ABSTRACT
The presence of trace water impurities in organic solvents can significantly influence chemical reactions and product quality; thus, the accurate detection of water content in these solvents is a critical requirement for industrial applications. Accordingly, an eco-friendly, effective, and economical sensor for detecting trace quantities of miscible water in organic solvents is required for industrial applications. In this study, we synthesized biomass-derived multi-atom-doped carbon dots (MACDs) as fluorescent probes and employed them for the detection of trace amounts of water impurities in several water-miscible organic solvents. The MACDs exhibited stable dual-color fluorescence emission under ultraviolet light irradiation and red and blue emissions in organic solvents and water. The fluorescence quantum yield was approximately 11 %, which indicates an excited intraparticle proton transfer response due to an increase in the water content within a wide response range from 0 % to 100 % (v/v) in organic solvents. The intensity of the red emission signal at 670 nm gradually decreased with an increase in the water content in the organic solvent. The MACDs could detect water with an instant response time of 55 s, a high sensitivity, and low limits of detection of 0.08 %, 1.36 %, 0.03 %, 0.04 %, 0.12 %, and 0.05 % (v/v) in ethanol, acetonitrile, dimethylformamide, methanol, isopropanol, and tetrahydrofuran, respectively. Hence, biomass-derived MACDs can serve as efficient and eco-friendly water sensors in organic solvents.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Spectrochim Acta A Mol Biomol Spectrosc
Assunto da revista:
BIOLOGIA MOLECULAR
Ano de publicação:
2024
Tipo de documento:
Article
País de publicação:
Reino Unido