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Dispersion-induced cooperative hydrogen atom transfer for radical iodoalkylation.
Zhu, Shaoqun; Jia, Lizi; Cheng, Qi; Han, Ying; Sun, Qiu; Yu, Huaguang; Chen, Xiaoyun; Hou, Hong.
Afiliação
  • Zhu S; School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225009, China. shaoqun.zhu@yzu.edu.cn.
  • Jia L; School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225009, China. shaoqun.zhu@yzu.edu.cn.
  • Cheng Q; School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225009, China. shaoqun.zhu@yzu.edu.cn.
  • Han Y; School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225009, China. shaoqun.zhu@yzu.edu.cn.
  • Sun Q; School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225009, China. shaoqun.zhu@yzu.edu.cn.
  • Yu H; Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, College of Optoelectronic Materials and Technology, Jianghan University, Wuhan 430056, China.
  • Chen X; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212005, China.
  • Hou H; School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225009, China. shaoqun.zhu@yzu.edu.cn.
Chem Commun (Camb) ; 60(77): 10772-10775, 2024 Sep 24.
Article em En | MEDLINE | ID: mdl-39252572
ABSTRACT
Described herein is a novel visible-light-promoted three-component radical iodo-alkylative cyclization of alkynes using iodoform as a bifunctional iodine atom source. Visible-light irradiation of a polar-polar interaction complex of iodoform with malonate enables the cooperative hydrogen atom transfer process to generate alkyl radical and trigger a cascade reaction sequence.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China País de publicação: Reino Unido
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China País de publicação: Reino Unido