Bio-based composite film from konjac flour and dialdehyde starch: Development, properties and structural features.

ABSTRACT

The development of environmental-friendly composite products from renewable resources has been considered as an excellent approach to address the negative impact of petroleum-based plastics on environment. Konjac flour (KF), as an excellent polysaccharide material, has a broad application in food field. It shows a promising future in the film field due to its excellent film-forming properties. In this work, KF was selected as primary film-forming matrix, and dialdehyde starch (DAS) as the reinforcing component. A series of KF/DAS composite films were prepared by adjusting the addition ratio of DAS component. Then, their physical and mechanical properties were characterized and analyzed. The results showed that KF/DAS composite film with 25 % DAS content exhibited the optimal mechanical properties, including tensile strength (TS) of 13.1 MPa and elongation at break (EAB) of 93.7 %, indicating that an excellent cross-linked system formed among KF and DAS utilizing the method described in this study. Furthermore, much evidences from the fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) confirmed that a strong chemical cross-linkages between DAS and KF via Schiff base and esterification reactions. Based on the thermogravimetry (TG) and scanning electron microscopy (SEM) results, KF/DAS composite films also had excellent thermal stability and a dense microstructure, although there are also changes with the DAS usage.