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Chinese Journal of Natural Medicines (English Ed.) ; (6): 783-788, 2016.
Artigo em Inglês | WPRIM | ID: wpr-812557

RESUMO

The present study was designed to construct the structurally diverse library of tetrahydroprotoberberines (THPBs) by combining the methods of chemical nonselective demethylation and microbial glycosylation. HPLC-MS/MS analyses tentatively identified 12 de-methylated and 9 glycosylated derivates of THPBs and 5 rarely oxidized glycosides of THPBs in the library. Through this effort, we achieved not only a variety of the THPBs and their glycosides but also tested the catalytic characteristics and capabilities of G. deliquescens NRRL 1086.


Assuntos
Alcaloides de Berberina , Química , Metabolismo , Biotransformação , Catálise , Gliocladium , Metabolismo , Glicosídeos , Química , Metabolismo , Glicosilação , Estrutura Molecular
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