RESUMEN
Livestock slurry has gathered significant interest as a secondary raw material for fertilisers industry due to its content on macronutrients -nitrogen, phosphorous, and potassium- and organic carbon. In this study, the performance of an on-site pilot plant composed by microfiltration, membrane-assisted stripping, and reverse osmosis for selective recovery of nitrogen as fertiliser and water reclamation was demonstrated for 2 years in a pig farm, referenced to 8 batches for seasonal assessment. Microfiltration mitigated the seasonal variation in the composition of pig slurry leading to stable process efficiency in the following steps. Membrane-assisted stripping resulted in the recovery of up to 56% of nitrogen as high-purity ammonium sulphate, and up to 42% of reclaimed water as reverse osmosis permeate. The proposed train of technologies reported proper performance and robustness during the whole demonstration period as it resulted in the production of reclaimed water and ammonium sulphate with no significant quality variations. The energy cost for both products obtained in this study was found in the average of the previous works reviewed with 12.49 kWh kg-1 NH3 produced, and 0.37 kWh m-3 of reclaimed water. The environmental assessment showed that nitrogen losses could be reduced by up to 90 kg N ha-1 d-1 by replacing manure spreading with precise fertilisation techniques, enabled by the selective recovery of nitrogen from SLF. Finally, the financial study showed that the scaling up of the proposed train of technologies would result in benefits for farms with more than 1600 pig heads.
RESUMEN
Livestock slurry has been reported to be a potential secondary raw material as it contains macronutrients nitrogen, phosphorus and potassium-, which could be valorised as high-quality fertilizers if proper separation and concentration of valuable compounds is performed. In this work, pig slurry liquid fraction was assessed for nutrient recovery and valorisation as fertilizer. Some indicators were used to evaluate the performance of proposed train of technologies within the framework of circular economy. As ammonium and potassium species are highly soluble at the whole pH range, a study based on phosphate speciation at pH from 4 to 8 was assessed to improve the macronutrients recovery from the slurry, resulting in two different treatment trains at acidic and alkaline conditions. The acidic treatment system based on centrifugation, microfiltration and forward osmosis was applied to obtain a nutrient-rich liquid organic fertilizer containing 1.3 % N, 1.3 % P2O5 and 1.5 % K2O. The alkaline path of valorisation was composed by centrifugation and stripping by using membrane contactors to produce an organic solid fertilizer -7.7 % N, 8,0 % P2O5 and 2.3 % K2O-, ammonium sulphate solution -1.4 % N- and irrigation water. In terms of circularity indicators, 45.8 % of the initial water content and <50 % of contained nutrients were recovered - 28.3 % N, 43.5 % P2O5 and 46.6 % K2O - in the acidic treatment resulting in 68.68 g fertilizer per kg of treated slurry. 75.1 % of water was recovered as irrigation water and 80.6 % N, 99.9 % P2O5, 83.4 % K2O was valorised in the alkaline treatment, as 219.60 g fertilizer per kg of treated slurry. Treatment paths at acidic and alkaline conditions yield promising results for nutrients recovery and valorisation as the obtained products (nutrient rich organic fertilizer, solid soil amendment and ammonium sulphate solution) fulfil the European Regulation for fertilizers to be potentially used in crop fields.