Morphology and dynamics of craterlike structures created by recoiling elongated particles.

We study the morphology and dynamics of craterlike structures formed when free-falling, randomly oriented, elongated particles bounce off a flat surface in a single particle scattering mode. The origin of a sharply defined rim with its associated structure, the factors determining the rim diameter, and the scaling of the diameter with impact velocity are examined. The probability distribution of rebounding particle ranges is calculated for a particular example and shown to provide a precursor description of structure formation.

Anisotropic water diffusion in nematic self-assemblies of clay nanoplatelets suspended in water.

Diffusion-weighted magnetic resonance imaging provides a vivid description of the little understood role played by interfacial interactions with macroscopic bodies in the cooperative self-assembly of clay nanoplatelets suspended in water. The interfacial interaction between hydrophilic glass walls and clay platelets in a Na-fluorhectorite gel can produce, for dilute gels, a face-to-wall anchoring of the platelets that leads to a uniaxial nematic order with platelet faces parallel to the walls but with randomly distributed normals of the faces. The application of a magnetic field perpendicular to the walls transforms this uniaxial order to an extended biaxial nematic order with orthogonal alignment between normals and the field. Moreover, for apolar walls, this face-to-wall anchoring is considerably hindered, and the uniaxial nematic order can be substantially disrupted.

Water ingress in Y-type zeolite: anomalous moisture-dependent transport diffusivity.

Nuclear magnetic resonance imaging measurements of liquid water ingress in a large number of nonactivated Y-type (Na) zeolite samples prepared under different conditions are reported on. Using an experimental arrangement that permits the application of Boltzmann's transformation of the 1D (one-dimensional) diffusion equation, the spatiotemporal scaling variables required for a collapse of the measured profiles into universal curves revealed subdiffusive behavior in all cases. It is shown that the one-dimensional fractal time diffusion equation constitutes a powerful tool to analyze the data and provides a connection between the moisture dependence of the effective transport diffusivities and the shapes of the universal curves. Thus, even for anomalous diffusion, the relationship between the universal curves and structural characteristics of the system; such as porosity, tortuosity of the pore space and, in some cases, the interplay between mesopores and nanopores can be addressed.

Scaling properties in the packing of crumpled wires.

Statistical properties of configurations of a metallic wire injected into a transparent planar two-dimensional cavity for three different injection geometries are investigated with the aid of high-resolution digital imaging techniques. The observed patterns of folds are studied as a function of the packing fraction of the wire within the cavity. In particular, we have examined the dependence of the mass of wire within a circle of radius R, as well as the dependence of the number of contacts wire-wire with the packing fraction. The distribution function n(s) of connected loops with internal area s formed as a consequence of the folded structure of the wire, and the average coordination number for these loops are also examined. Several scaling laws connecting variables of physical interest are obtained and discussed and a relation of this problem with disordered two-dimensional foam and random packing of disks is examined.

Crumpled wires in two dimensions.

Geometric and statistical properties of wires injected into a two-dimensional cavity with three different injection geometries are investigated. Complex patterns of folds are observed and studied as a function of the length of the wire. The mass-size relation and the distribution function n(s) of loops with internal area s formed as a consequence of the folded structure of the wire are examined. Several scaling laws are found and a hierarchical model is introduced to explain the experimental behavior observed in this two-dimensional crumpling process.

Mobility and free radical concentration effects in proton-electron double-resonance imaging.

The dependence of the enhancement of proton-electron double-resonance images upon the mobility of the proton bearing molecules, of the concentration of free radicals, and of the pulsed saturating RF power is studied in a magnetic field of 16 mT. The data exhibit a behavior which, in the potentially interesting region of small free radical concentration, may differ substantially from the high-concentration regime depending upon experimental conditions. The results permit a clearer understanding of the factors determining enhancement and contrast in images obtained by dynamic nuclear polarization.