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The influence of residual cuts on the deactivation of hierarchical Y zeolite-based catalysts during the co-processing of vacuum gas oil (VGO) with atmospheric residue (ATR) was investigated. The experiments were conducted in a laboratory-scale MAT-type reactor. The conversion of VGO, ATR, and their 70:30 (mass basis) mixture was examined using two composite catalysts: Cat.Y.0.00 and Cat.Y.0.20. The operating conditions closely resembled those of the commercial catalytic cracking process (550 °C and contact times of 10 to 50 s). When ATR was processed individually, the conversion remained below 50 wt%. However, significant improvements in conversion rates were achieved and catalyst deactivation was mitigated when ATR was co-processed with VGO. Notably, the BET surface area and average mesopore volume were adversely impacted by ATR, which also led to the accumulation of high levels of metals and nitrogen on the spent catalyst, detrimentally affecting its acidic and structural properties. Moreover, substantial coke deposition occurred during ATR cracking. The soluble and insoluble coke analysis revealed H/C ratio values of up to 0.36, indicative of polycondensed coke structures with more than ten aromatic rings. The nature of the coke was confirmed through TPO and FTIR analyses. Interestingly, the CatY.0.20 catalyst exhibited less activity loss, retaining superior acid and structural properties. Co-processing Colombian atmospheric residue with ATR loadings of 30 wt% (higher than the typical 20 wt%) in catalysts formulated with hierarchical zeolites presents a promising alternative for commercial applications. This research opens avenues for optimizing catalytic cracking processes.
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This study investigated the deactivation and regeneration of hierarchical zeolites in vacuum gas oil conversion, aiming to reach the equilibrium state seen in fluidized bed catalytic cracking (FCC). The research utilized various characterization techniques to analyze the properties of zeolites before and after coking and regeneration. Zeolite Y-0.20-S was found to have the highest gasoline selectivity and quality, mirroring industrial yields, and displayed notable stability across deactivation/regeneration cycles. Higher mesopore concentration in zeolites led to increased coke selectivity and better resistance to deactivation. The study observed a dominance of aromatic coke with a higher degree of condensation in these zeolites. Despite coke deposition affecting acid and textural properties, the regeneration process effectively restored these characteristics, proving its efficiency. The zeolites with greater mesoporosity retained their fundamental properties responsible for activity and selectivity, highlighting the importance of selecting materials that provide high conversions and maintain stability and product selectivity over multiple cycles. The Y-0.20-S zeolite, in particular, was identified as a promising candidate for commercial catalyst development for gasoline production, contributing to the FCC process's energy efficiency.
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In this paper, the development of a 3D adaptive probabilistic explicit cracking model for concrete is reported. The contribution offered herein consists in a new adaptive mesh strategy designed to optimize the use of interface elements in probabilistic explicit cracking models. The proposed adaptive mesh procedure is markedly different from other strategies found in the literature, since it takes into account possible influences on the redistribution of stresses after cracking and can also be applied to purely deterministic cracking models. The process of obtaining the most appropriate adaptive mesh procedure involved the development and evaluation of three different adaptivity strategies. Two of these adaptivity strategies were shown to be inappropriate due to issues related to stress redistribution after cracking. The validation results demonstrate that the developed adaptive probabilistic model is capable of predicting the scale effect at a level similar to that experimentally observed, considering the tensile failure of plain concrete specimens. The results also show that different softening levels can be obtained. The proposed adaptive mesh strategy proved to be advantageous, being able to promote significant reductions in the simulation time in comparison with the classical strategy commonly used in probabilistic explicit cracking models.
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The performance of catalysts prepared from hierarchical Y zeolites has been studied during the conversion of vacuum gas oil (VGO) into higher-value products. Two different catalysts have been studied: CatY.0.00 was obtained from the standard zeolite (Y-0.00-M: without alkaline treatment) and CatY.0.20 was prepared from the desilicated zeolite (Y-0-20-M: treated with 0.20 M NaOH). The cracking tests were carried out in a microactivity test (MAT) unit with a fixed-bed reactor at 550 °C in the 20-50 s reaction time range, with a catalyst mass of 3 g and a mass flow rate of VGO of 2.0 g/min. The products obtained were grouped according to their boiling point range in dry gas (DG), liquefied petroleum gas (LPG), naphtha, and coke. The results showed a greater conversion and selectivity to gasoline with the CatY.0.20 catalyst, along with improved quality (RON) of the C5-C12 cut. Conversely, the CatY.0.00 catalyst (obtained from the Y-0.00-M zeolite) showed greater selectivity to gases (DG and LPG), attributable to the electronic confinement effect within the microporous channels of the zeolite. The nature of coke has been studied using different analysis techniques and the impact on the catalysts by comparing the properties of the fresh and deactivated catalysts. The coke deposited on the catalyst surfaces was responsible for the loss of activity; however, the CatY.0.20 catalyst showed greater resistance to deactivation by coke, despite showing the highest selectivity. Given that the reaction occurs in the acid sites of the zeolite and not in the matrix, the increased degree of mesoporosity of the zeolite in the CatY.0.20 catalyst facilitated the outward diffusion of products from the zeolitic channels to the matrix, thereby preserving greater activity.
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Cow dung (CD) is a material that has been used for millennia by humanity as a stabilizer in earth building techniques in vernacular architecture. However, this stabilization has been little addressed scientifically. In this study, the effect of CD additions was assessed on earth mortars produced with one type of earth from Brazil and two other types from Portugal (from Monsaraz and Caparica). The effect of two volumetric proportions of CD additions were assessed: 10% and 20% of earth + sand. The German standard DIN 18947 was used to perform the physical and mechanical tests, and classify the mortars. In comparison to the reference mortars without CD, the additions reduced linear shrinkage and cracking. An increase in flexural and compressive strengths was not observed only in mortars produced with earth from Monsaraz. In mortars produced with the earth from Caparica, the addition of 10% of CD increased flexural strength by 15% and compressive strength by 34%. For mortars produced with the earth from Brazil, the addition of 10% of CD increased these mechanical strengths by 40%. The increase in adhesive strength and water resistance promoted by the CD additions was observed in mortars produced with all three types of earth. Applied on ceramic brick, the proportion of 10% of CD increased the adherence by 100% for the three types of earth. Applied on adobe, the same proportion of CD also increased it more than 50%. For the water immersion test, the CD additions made possible for the mortar specimens not to disintegrate after a 30 min immersion, with the 20% proportion being more efficient. The effects of the CD on mechanical performance, including adhesion, were more significant on the tropical earth mortars but the effects on water resistance were more significant on the Mediterranean earthen mortars. CD has shown its positive effects and potential for both tropical and Mediterranean earthen plasters and renders tested, justifying being further studied as an eco-efficient bio-stabilizer.
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The use of tools played a central role in human culture and evolution. Early studies with apes demonstrated the tool use; however, currently the works have focused on Platyrrhine, particularly capuchin monkeys. Blonde capuchin monkeys, Sapajus flavius, have been observed using sticks to fish for termites in the Atlantic Forest, where this species has been extensively studied. In this study, we presented the first evidence of stone tool use by the blonde capuchin monkeys, as well as the dimensions and weight of these tools. We gathered data from three areas of Caatinga dry forest where we discovered this new tool use among the species. The mean weight of the hammers was 475.7 g (± 142 SD). The mean height of the anvils was 48.3 cm (± 18.7 SD), while the mean surface area of the anvils was 1.2 m2 (± 0.4 SD). We identified fruits and/or nuts from three plant species-Prunus dulces, Cnidoscolus quercifolius, and Syagrus coronate-near the anvils at the study sites. Additionally, we passively observed six instances of stone tool use by blonde capuchin monkeys. Their use of stones to crack encased foods mirrored behaviors previously reported in Sapajus libidinosus, a species well known for using stone tools to exploit hard nuts. Our findings place blonde capuchin monkeys among the list of primates that utilize stones as tools, highlighting the species' adaptability in exploiting resources within the Caatinga. Long-term studies are essentials to comprehend the use pattern of stone tools (across both general and seasonal perspectives) and the influence of variables, such as fruit hardness, distance to watercourses, and fruit availability on the use of this technology by this primate.
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Sapajus , Comportamento de Utilização de Ferramentas , Animais , Comportamento Alimentar , Brasil , Feminino , Masculino , Frutas , Nozes , Cebinae/fisiologiaRESUMO
Electronic flexible devices are prone to degrade their electrical performance or lose functionality when subjected to deformations. Brittle fracture is a common damaging effect observed in devices composed of low-thickness layered materials stacked onto a flexible substrate by dissimilar mechanical properties interaction. This work studies the mechanical behavior of Organic Flexible Solar Cells (OFSC) with a heterostructure PET/ITO/P3HT:PCBM/Ag subjected to uniaxial displacements through an experimental and numeric point of view. Experimental showed that damage proceeds in two ways. First, the formation of a grid crack pattern begins at the ITO layer, and second, the delamination in the ITO/P3HT:PCBM interface. The numerical model analyzed the force and displacements and the absorption/dissipation of strain energy on layers and interfaces of the device. The comparison of the global Young's module for experimental and numeric studies validated the numeric analysis, with results of 4.16 ± 0.05 GPa for experimental and 4.36 ± 0.15 GPa for numeric. Additionally, the model associates the ITO layer with the highest strain energy dissipation or the most prone to failure, which agrees with the experiments. Then, the model successfully predicts the mechanical behavior of OFSC and represents a valuable tool for studying flexible devices and predicting the appearance of mechanical damage when subjected to uniaxial deformations, even being able to avoid potential damage changing parameters such as the thickness of the layers.
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Populations of bearded capuchin monkeys (Sapajus libidinosus) vary in their tool use behaviors, with some of this divergence regarded as culturally determined. The use of stone tools, primarily to crack open encased foods, is widespread among bearded capuchins living in dry habitats (Caatinga and Cerrado). Significant diversity in targets, processed foods, material, and size of tools is observed across populations. However, so far, only a few sites have been systematically studied, and we are still distant from a representative picture of the range of variation in capuchins' culture. In this study, we did a systematic assessment of stone tool use sites in the Ubajara National Park (UNP), in the Caatinga region of Ceará, Brazil, recording and measuring stone tools, processed foods, and available lithic resources as part of an extensive comparative research, the CapCult project. We found indirect and direct evidence that capuchin monkeys at UNP customarily use hammerstones and anvils to process at least two species of palm nuts, macauba (Acrocomia aculeata) and the harder babaçu (Attalea speciosa). Most of the anvils were rock surfaces and had leftovers of only one palm nut species. The hammerstones used to process both palm nuts were not significantly different in weight, although the ones used for Ac. aculeata were longer. We found a higher frequency of nut-cracking sites in the drier lowland area of the park, reflecting differences in the density of the most common palm species, Ac. aculeata, and availability of raw stone material. The stone tool use observed in UNP is within the scope of previously reported in savannah capuchin populations. Our study widens the knowledge of stone tool-use diversity in wild capuchin monkeys, which could contribute to shaping conservation policy, including cultural traits.
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Arecaceae , Cebinae , Comportamento de Utilização de Ferramentas , Animais , Nozes , Cebus , Brasil , Parques RecreativosRESUMO
A great complexity limits its use as the degree of aging of the asphalt binder of the RAP is a determinant for the interaction with the new binder and recycling agents to design asphalt mixtures with reclaimed asphalt pavement (RAP). One of the ways to analyze the level of interaction between the aged binder and the recycling agent is through the analysis of the performance of the mixtures after the accelerated aging of the samples in the laboratory. Thus, this paper evaluated the mechanical performance of asphalt mixtures with high contents of RAP (50%, 75%, and 100%) and organic type recycling agents (residual engine oil) and surfactant (ADCAP WM), submitted to aging protocols short and long term. The data obtained verified the feasibility of adding up to 75% of RAP in the recycled mixtures. However, detailed monitoring of its execution and performance throughout its useful life is necessary. Fatigue and flexural fracture data were highly altered by aging conditioning, evidencing the reduction in the performance of the compositions of the recycled mixtures. The statistical test showed significance for the parameters RAP content and type/content of the recycling agent used. In addition, there was an increase in the deformation capacity and better resistance to aging and cracking with the incorporation of the surfactant recycling agent.
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Hidrocarbonetos , Laboratórios , Reciclagem , TensoativosRESUMO
The Barcelona method was developed as an alternative to other tests for assessing the post-cracking behavior of fiber-reinforced concrete, with the main advantage being that it uses significantly smaller specimens compared to other methods. For this reason, it can provide a solution for characterizing concrete in hard-to-reach constructions such as roads and tunnels. On the other hand, polypropylene (PP) fibers have gained increased attention in recent years within the scientific community due to their high tensile strength and cost-effectiveness. This research aimed to understand the influence of PP fiber volume, slenderness (l/d), and reinforcement index on post-cracking properties of concrete, including toughness and residual strength (f_res), using the Barcelona method. Three fiber volumes, 0.4%, 0.8%, and 1.2%, and three slenderness ratios, 46.5, 58.1, and 69.8, were employed in normal-strength concrete. In addition to the reference mixture without fibers, 10 mixtures were prepared with 10 specimens each, resulting in a total of 100 specimens. Pearson's hypothesis test was employed to determine the existence of correlations between variables, followed by scatter plots to generate predictive equations between post-cracking properties and fiber attributes. The results indicated no direct correlation between fiber slenderness and post-cracking properties. Regarding fiber volume, there was a correlation with residual strength but not with toughness. However, the combined effect of volume and slenderness, the reinforcement index, correlates with the post-cracking properties of concrete. Finally, four predictive equations for toughness and residual strength were derived based on the reinforcement index. These equations can prove valuable for designing structures made of polypropylene fiber-reinforced concrete.
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In this study, zeolites (Z) were used as catalysts in the cracking of a Colombian vacuum gas oil (VGO), with a focus on product distribution and coke deposition. The catalytic tests were carried out in a MAT-type reactor under typical conditions. The zeolites were subjected to alkaline treatment with NaOH at concentrations ranging from 0.05 to 0.4 mol/L, resulting in the creation of several samples (Z-0.05, Z-0.10, Z-0.20, Z-0.30 and Z-0.40) that were then hydrothermally stabilized (Z-0.05-M, Z-0.10-M, Z-0.20-M, Z-0.30-M and Z-0.40-M) to increase mesoporosity and reduced crystallinity. The increase in mesoporosity was accompanied by an improvement in acidity. Despite Z-0.30-M having higher acidity, Z-0.00-M and Z-0.10-M exhibited the highest activity due to their high crystallinity and microporosity, yielding the highest gas yields. Gasoline was the main product, with maximum yields exceeding 30%. Z-0.20-M produced more aromatic and olefin compounds than the others, resulting in higher quality gasoline. Coke formation followed the trend: Z-0.00-M < Z-0.10-M < Z-0.20-M < Z-0.30-M. The higher intracrystalline mesoporosity in the zeolites favored the formation of a more condensed coke.
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This study proposes a novel test method and corresponding procedure to evaluate how coconut fibres affect crack propagation rates resulting from plastic shrinkage during the accelerated drying of concrete slabs. The experiment employed concrete plate specimens, which were used to simulate slab structural elements with a surface dimension notably greater than their thickness. These slabs were reinforced with coconut fibre with 0.5%, 0.75%, and 1% fibre content. A wind tunnel was designed to simulate two significant climate parameters (wind speed and air temperature), which could impact the cracking behaviour of surface elements. The proposed wind tunnel allowed air temperature to be controlled alongside wind speed while monitoring moisture loss and the cracking propagation process. During testing, a photographic recording method was used to evaluate cracking behaviour, with the total crack length serving as a parameter to assess the impact of fibre content on the crack propagation of slab surfaces. Additionally, crack depth was measured using ultrasound equipment. The results indicate that the proposed test method was appropriate for future research, allowing for the evaluation of the effect of natural fibres on the plastic shrinkage behaviour of surface elements under controlled environmental conditions. Based on initial studies and the results obtained through the proposed test method, concrete containing 0.75% fibre content exhibited significantly reduced crack propagation on slab surfaces, as well as a reduction in the crack depth caused by plastic shrinkage during the early age of the concrete.
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The hydrocarbon industry constantly requires a better understanding of stainless-steel welding metallurgy. Despite the fact that gas metal arc welding (GMAW) is one of the most commonly employed welding processes in the petrochemical industry, the process is characterized by the presence of a high number of variables to control in order to obtain components that are dimensionally repeatable and satisfy the functional requirements. In particular, corrosion is still a phenomenon that highly affects the performance of the exposed materials, and special attention must be paid when welding is applied. In this study, the real operating conditions of petrochemical industry were reproduced through an accelerated test in a corrosion reactor at 70 °C for 600 h, exposing robotic GMAW samples free of defects with suitable geometry. The results show that, even if duplex stainless steels are characterized for being more corrosion resistant than other stainless steels, under these conditions it was possible to identify microstructural damage. In detail was found that the corrosion properties were strongly related to the heat input during welding and that the best corrosion properties can be obtained with the higher heat input.
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The construction industry requires concrete with adequate post-cracking behavior for applications such as tunnels, bridges, and pavements. For this reason, polypropylene macrofibers are used, which are synthetic fibers that fulfill the function of providing residual strength to concrete. In this study, an experimental plan is carried out to evaluate the bending behavior of concrete reinforced with polypropylene fibers using the four-point bending test according to ASTM C1609. Three fiber dosages (3.6, 7.2 and 10.8 kg/m3) and three fiber lengths (40, 50, and 60 mm) were used. The use of macro polypropylene fibers increased the post-cracking behavior of concrete. In addition, based on the experimentally obtained results and available literature data, a multivariable equation was developed to predict the concrete toughness as a function of the volume, slenderness, and modulus of elasticity of the fibers. A Pearson's correlation coefficient, r of 0.90, showed a strong correlation between the developed equation and the experimental data. From this equation, it was possible to determine the participation of the following parameters in calculating toughness. The participation or weight of the fiber's modulus of elasticity on the concrete's tenacity is 26%, the volume of the fiber is 39%, the slenderness is 19%, and the reinforcement index is 16%.
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Asphalt rubber mixtures have been used as pavement surface layers due to their ability to prevent early degradation, and are considered a sustainable option. This study performed analysis comparing the fatigue resistance of asphalt rubber mixtures of different combinations of asphalt bases, crumb rubber, and gradation, in order to estimate the performance of asphalt rubber mixtures as pavement surface layers. The methodology was developed in a laboratory and involved asphalt rubber production by continuous and terminal blend systems with different crumb rubbers and asphalt base types. Asphalt rubber mixtures with varying gradations and an unmodified asphalt mixture as a reference were produced. The mechanical behavior as a dynamic modulus and with respect to fatigue resistance was evaluated using a four-point bending test. In order to verify each of the asphalt rubber mixtures' contribution as a surface layer, pavement structures were designed and their lifespans were compared. The findings showed that all asphalt rubber mixtures presented higher fatigue resistance than the reference. For pavement design, in comparison with the reference mixture, the thickness of the surface layer could be reduced by at least 50% while achieving the same life, proving its successful performance. This study demonstrated the effective contribution of crumb rubber from scrap tires as an asphalt modifier for producing sustainable mixtures with adequate fatigue performance.
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Mode I fracture (tensile type) is the common cracking mode of asphalt pavements, which is caused by thermal cyclic loading or traffic. Some studies allow the analysis of the fracture modes by means of standardized tests, some of which are limited, difficult, with little repeatability or do not generate an adequate tension state. In this paper, mode I fracture toughness of asphalt mixtures with symmetric geometry specimens at intermediate temperature is evaluated. Experimental results from direct tension test and simulations on asphalt mix specimens subjected to intermediate temperatures of 10, 20 and 30 °C, mode I load rates (0.5, 1 and 2 mm/min) and notches (2 and 3 cm) were compared to find the variables that reflect the operating conditions of the asphalt mix. Results showed that shear stresses are 8.12% lower in the simulations with respect to the tests, while the load-deformation curves show 30% and 35% variation, where the temperature of 20 °C, the notch of 2 cm and the loading speed of 1 mm/min are the conditions that best represent the stress state of the test; moreover, it manages to consider the elastic and viscous components of the material.
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This work presents an experimental methodology developed to perform fatigue crack growth (FCG) and slow strain rate (SSR) tests in ethanol environments aiming to evaluate stress corrosion cracking (SCC) susceptibility of circumferential welds on steel pipelines. FCG and SSR specimens were machined from a welded pipe and the notches were properly designed to promote crack propagation in the different regions of the weld. Tests were carried out keeping the crack-tip region fully immersed in an ethanol solution, which was fueled by a circulation system to ensure replenishment and aeration throughout the test. When applied to a welded API X70 steel pipe, this experimental methodology proved to be an efficient and simple method to achieve relevant and important informations on environmentally assisted crack growth and SCC susceptibility. The method developed here is inserted in the aspects as follows:â¢Perform tests in slow strain rate and cyclic bend loading in circulating ethanol, to promote the fracture in the different regions of a circumferential weld joint of a steel pipe.â¢Investigate sensitivity to stress corrosion cracking (SCC) of these different weld regions in ethanolic environment.â¢This method presents constructive details of a suitable apparatus which the experiments can be easily replicated.
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Adequately predicting overlay behaviour is essential for flexible pavement rehabilitation to reach the predicted lifespan. Reflective cracking is one of the main failure mechanisms affecting overlay performance. This failure may occur due to cracks in the lower layers that propagate to the overlay due to traffic loads, temperature variations, shrinkage cracking of cement-treated layers, and subgrade movements. This work aims to assess the reflective cracking phenomenon of asphalt rubber mixtures as an overlay through laboratory tests and numerical simulation. Four-point bending equipment and the reflective crack device were used to perform the laboratory tests. A numerical simulation through the finite element method was accomplished to estimate the von Mises strain and develop reflective cracking fatigue laws. The results showed that the asphalt rubber mixtures are suitable for extending overlay lifespan considering reflective cracking. The evaluated asphalt rubber mixtures presented reflective cracking resistance almost eight times greater than the conventional ones.
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Coarctation of the abdominal aorta is a rare etiology of intermittent claudication and refractory hypertension. Treatment is complex and requires knowledge of several vascular reconstruction techniques. We report a case of aortic coarctation at the level of the renal arteries, describing its treatment and presenting a literature review. Female patient, 65 years old, with refractory hypertension since the age of 35, using five antihypertensive medications at maximum doses. Blood pressure was 260/180mmHg and she had disabling claudication (less than 20 meters). Computed tomography angiography showed a 4mm coarctation in the juxtarenal aorta, with circumferential calcification at the stenosis site, and tortuous infrarenal aorta. Hybrid repair was performed with an iliac-birenal bypass and implantation of an Advanta V12 stent at the stenosis site. The patient's postoperative course was satisfactory, she was free from claudication, and her blood pressure 60 days after surgery was 140/80mmHg, taking two antihypertensive medications.
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Resumo Coarctação da aorta abdominal é uma causa rara de claudicação de membros inferiores e hipertensão refratária. O tratamento é complexo e exige conhecimento de diversas técnicas de reconstrução vascular. Apresentamos um caso de coarctação ao nível das artérias renais, seu tratamento e revisão da literatura. Paciente feminina, 65 anos, com hipertensão refratária desde os 35 anos, utilizando cinco medicações anti-hipertensivas em dose máxima. Pressão arterial média de 260/180mmHg e claudicação incapacitante (menos de 20 metros) bilateral. Angiotomografia computadorizada demonstrou coarctação de aorta justarrenal de 4 mm de maior diâmetro, calcificação circunferencial no local da estenose e tortuosidade da aorta infrarrenal. Foi submetida a tratamento híbrido, com ponte ilíaco-birrenal e implante de stent Advanta V12 no local da estenose. A paciente evoluiu satisfatoriamente e, 60 dias depois da cirurgia, apresentava-se com uma pressão arterial de 140/80mmHg, em uso de apenas duas medicações anti-hipertensivas e sem claudicação.
Abstract Coarctation of the abdominal aorta is a rare etiology of intermittent claudication and refractory hypertension. Treatment is complex and requires knowledge of several vascular reconstruction techniques. We report a case of aortic coarctation at the level of the renal arteries, describing its treatment and presenting a literature review. Female patient, 65 years old, with refractory hypertension since the age of 35, using five antihypertensive medications at maximum doses. Blood pressure was 260/180mmHg and she had disabling claudication (less than 20 meters). Computed tomography angiography showed a 4mm coarctation in the juxtarenal aorta, with circumferential calcification at the stenosis site, and tortuous infrarenal aorta. Hybrid repair was performed with an iliac-birenal bypass and implantation of an Advanta V12 stent at the stenosis site. The patient's postoperative course was satisfactory, she was free from claudication, and her blood pressure 60 days after surgery was 140/80mmHg, taking two antihypertensive medications.