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Chemosphere ; 253: 126754, 2020 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-32302914

RESUMO

This study sought to analyze the effect of curing temperature on mechanical strength and microstructure of a copper tailing-based geopolymer via scanning electron microscopy (SEM), HCl extraction, nuclear magnetic resonance (NMR), and X-ray diffraction (XRD). The distribution of gel formed in geopolymers tended to be uniform with increasing curing temperature from 25 to 80 °C. Moreover, the percentage of Si sites in C-S-H and N-A-S-H gels increased from 62.08% to 78.94% and more tetrahedral [AlO4] was incorporated into the tetrahedron [SiO4] backbone, leading to an increase of compressive strength from 10.2 to 39.6 MPa. When the curing temperature was increased to 120 °C, the percentage of Si sites in C-S-H and N-A-S-H gel decreased to 69.52%, and the compressive strength decreased to 27.5 MPa. Moderately elevated curing temperature promoted the dissolution of aluminosilicate while curing temperatures above 80 °C hindered it. Excessive curing temperature led to a decrease in the geopolymer alkaline medium.


Assuntos
Silicatos de Alumínio/química , Materiais de Construção/análise , Cobre/química , Resíduos Industriais/análise , Gerenciamento de Resíduos/métodos , Força Compressiva , Microscopia Eletrônica de Varredura , Mineração , Propriedades de Superfície , Temperatura , Difração de Raios X
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